When you load up IRC, you'll have your mIRC options popup.
Under Category, look for Servers and go to Add. Add the irc.quakenet.org as a new server. Once you've done that, you can go to your server window and either quick connect OR typing in /server irc.quakenet.org (this is pointless if you added the server to your options to access in the future.)
Make sure that you have a nickname setup in mIRC already. Once you're connected, in the status bar, type in '/join #talkfreelance' (without the quotes.) All done.
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